Abstract
AbstractWe report the straightforward synthesis and full characterization of a novel series rhodium(I) complexes (3 a–c) supported by hydroxyl‐functionalized 1,2,3‐triazolylidenes. All new compounds were fully characterized by means of 1H and 13C NMR spectroscopy, melting points, and elemental analyses. The new triazolylidene rhodium complexes 3 a–c were tested as catalysts in the hydrosilylation of terminal alkynes and the 1,4‐addition of boronic acid to 2‐cyclohexenone. Both catalytic processes provide good to excellent yields under low catalyst loadings and in the case of the hydrosilylation, a good selectivity toward the E‐isomer is observed.
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