Abstract
Complete regioselective 1,6-hydrosilylation of dimethyl cis, cis-muconate took place by using trialkylsilanes in the presence of RhCl(PPh 3) 3 as a catalyst. The novel, functionalized ketene silyl acetal thus obtained exhibited moderate electrophilic properties. Hydrosilylation of trans, trans-muconate under similar conditions gave only a 3,4-adduct, whereas that of trans, cis-muconate resulted in a complicated mixture of adducts but for a 1,6-adduct.
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