Abstract
A rhodium‐catalyzed chemo‐, regio‐ and enantioselective intermolecular coupling reaction of 2‐aminobenzothiazoles with terminal allenes is reported. The new reaction displays a wide substrate scope for both reaction partners to deliver the allylation products in good yields, with excellent regio‐ and enantioselectivity. This novel methodology was further applied in an efficient synthesis of chiral isothiourea.
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