Abstract
Although vinyl azide is an important class of functional group that possesses diverse reactivities and is a convenient synthon for N-heterocycles, cyclic vinyl azide remains underdeveloped due to difficult preparation. This work discloses a rhodium catalyzed intramolecular [4 + 2] cycloaddition reaction that can afford challenging fused bicyclic vinyl azides efficiently in ambient conditions and paves a facile route for the research in the chemistry of cyclic vinyl azides.
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