Abstract
The rhodium(III) distibine complexes trans-[Rh(L-L) 2X 2]Y (L-L = Ph 2Sb(CH 2) 3SbPh 2 or o-C 6H 4(SbMe 2) 2: X = Cl, Br or I; Y = X or BF 4) have been prepared and studied by UV-Vis, 1H and 104Rh NMR spectroscopies and electrospray mass spectrometry. The 103Rh NMR spectroscopic data are reported and compared with data on related phosphine and arsine complexes. The single crystal X-ray structure of trans-[Rh(Ph 2Sb(CH 2) 3SbPh 2] 2Cl 2][ClO 4] is reported RhSb = 2.594(2), 2.611(2); RhCl = 2.369(7) A ̊ ) .
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