Abstract

Making C-C from C-H: [{RhCp*Cl(2)}(2)]/AgSbF(6) (Cp*=pentamethylcyclopentadienyl) can regioselectively catalyze the C-C coupling of arenes with aziridines by a C-H activation pathway. An eight-membered rhodacyclic intermediate resulting from the insertion of the Rh-C bond into the aziridine was isolated.

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