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Abstract
Cleavage of [{Rh(diolefin)Cl}2] by bidentate heterocyclic chelating ligands (LL) has been studied, and diolefin neutral, ionic or ion-pair type compounds are formed depending on the ligands and/or the Rh: (LL) ratio employed. When the reactions are performed in media saturated with CO and with Rh: (LL)=2∶1, only carbonylated ion-pair complexes are formed. The diolefin compounds react with tin(II) chloride yielding species containing trichlorostannato-groups. Subsequent reaction with CO leads to displacement of the diolefin and formation of the corresponding dicarbonyl species.
Published Version
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