Abstract

AbstractThe rhodium(I)‐catalyzed intramolecular [2+2+2] cycloaddition between allenes, alkynes, and imines has been developed. This cyclization proceeds via a strained azarhodacycle, giving a 5,7‐fused cyclic amide or a tricyclic product containing an 8‐azabicyclo[3.2.1]octane skeleton in high yield.magnified image

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