Abstract
AbstractHerein we disclose an uncommon Rhodium(III)‐catalyzed C2‐selective functionalization of N‐(2‐Pyrimidyl)indole with internal alkynes. Excess amounts of silver acetate (5.0 equiv.) were found to be crucial for the efficient C2 naphthylation and C2 enol esterification of indoles. In sharp contrast, 2.0 equivalents of silver acetate resulted in the C−H alkenylation only. Control experiments were also carried out to briefly study the mechanism of this transformation.magnified image
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
