Abstract
The rhodium and iridium fluorido bifluorido complexes trans‐[Rh(4‐C5F4N)(F)(FHF)(CNtBu)(PEt3)2] (1) and trans‐[Ir(4‐C5F4N)(F)(FHF)(CNtBu)(PiPr3)2] (2) have been synthesized by protonation of the peroxido complexes trans‐[M(4‐C5F4N)(O2)(CNtBu)(PR3)2] with an HF source (M = Rh, R = Et; M = Ir, R = iPr). Abstraction of the coordinated HF resulted in the formation of the difluorido compounds trans‐[M(4‐C5F4N)(F)2(CNtBu)(PR3)2] (4: M = Rh, R = Et; 5: M = Ir, R = iPr).
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