Rheology and microstructure of discontinuous shear thickening suspensions

Abstract

We report experimental studies on rheology and microstructure in discontinuous shear thickening of fumed silica suspensions. Formation of particle clusters was observed after the critical shear rate, and their size increases during shear thickening. At higher shear rates, these clusters were found to break down due to strong shear forces, and a continuous decrease in viscosity was observed. The suspension viscosity and the first normal stress difference variation with the shear rate showed similar dependence. The sign of first normal stress difference was negative during shear thickening, which is consistent with the hydrodynamic model of cluster formation. A linear variation of the first normal stress difference with shear rate during shear thickening further indicates its predominant hydrodynamic origin and supports the recent Stokesian dynamics simulation studies on discontinuous shear thickening based on the hydrodynamic model of nonsmooth colloids by Wang et al. [J. Rheol. 64, 379–394 (2020)]. On the other hand, a nonlinear decrease in the first normal stress difference with shear rate in the second shear-thinning region is primarily due to breaking of large clusters into smaller ones and with a possibility of frictional contacts within these hydroclusters. The oscillatory shear measurements were also performed and the samples displayed strain thickening similar to shear thickening. The similarity between the steady and dynamic shear rheology at high strain amplitudes was observed using the modified Cox–Merz rule.