Abstract

Measurements were taken of both viscous and elastic properties of polystyrene melts, using a capillary rheometer recently constructed byHan. The viscous property is determined from the slope of the axial pressure distribution, and the elastic property is determined from the exit pressure, which is obtained at the tube exit when the straight line portion of the axial pressure profile is extrapolated to the exit of the tube. Previous studies ofHan demonstrated that the exit pressure thus obtained can be correlated with die swell ratios, and that the exit pressure is equal to the normal stress difference for polymer melts in fully developed viscometric flow. The present study of polystyrene melts corroborates all previous correlations obtained with high density polyethylene and polypropylene melts as regard the exit pressure measurements. A salient feature of the method employed here is that it requires only a single capillary, long enough to assure that flow is fully developed.

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