Rheological demonstration of alteration in the heavy crude oil fluid structure upon addition of nanoparticles

Abstract

Nanotechnology offers potentially disruptive methods to improve the mobility of heavy oil through viscosity reduction. In this sense, the objective of this work is to probe changes in the viscoelastic network of asphaltenes intrinsic to heavy oil structure upon addition of fumed SiO2 nanoparticles, using dynamic rheological techniques. The effects of the addition of nanoparticle (100, 1000 and 10,000mg/L) on heavy oil are patently reflected as a viscosity reduction (for shear rates between 0 and 100s−1) and a non-Newtonian shear thinning behavior. The best concentration of nanoparticles over the wide range evaluated is obtained at 1000mg/L, which was evaluated at 288, 298 and 313K. The viscosity reductions were found to range from 12 to 45% in the shear rate range 0–100s−1. The linear viscoelastic region (LVR) was determined by running an amplitude sweep test at 10rad/s and 298K. Viscoelastic moduli were measured in dynamic tests in a frequency range from 0.1 to 100rad/s at a strain of 2% and at temperatures of 288, 298 and 313K. For heavy crude oil without nanoparticles, the magnitude of the loss modulus G″ and its growing trend suggest the existence of a viscoelastic network of asphaltenes and auto-associative behavior. For all tests, the loss modulus, G″, is always greater than the storage modulus G′, suggesting that the crude oil is more viscous than elastic, except at 313K and at a frequency > 30rad/s, where G′ is greater than G″. By adding 1000mg/L of nanoparticles, the magnitude of the viscoelastic moduli is reduced compared to values for crude oil without nanoparticles. The results conclusively prove that nanoparticles disrupt the viscoelastic network formed by asphaltenes aggregates in the presence of resins, and this causes the viscosity reduction in heavy crude oil. This conclusion is further supported by results obtained when nanoparticles were added to de-asphalted oil (DAO) and light oil with a low asphaltene content; in both cases the viscosity increases, suggesting that the nanoparticles interact directly with asphaltenes in crude oil. Effects are observed if asphaltenes are present at high enough concentration.