Rheological and Crystallization Properties of ABS/PA6-Compatibilized Blends via In Situ Reactive Extrusion.

Abstract

ABS/PA6-compatibilized blends were prepared by in situ reactive extrusion method. The main objective was to evaluate the influences of the morphology and blend composition on the rheological and nonisothermal crystallization properties. The morphology of submicron-sized ABS droplets evenly dispersed in PA6 led to dilatant fluid behavior and a transition from elastic to viscous behavior in the low-frequency region. The crystallization results indicated that reactive blends had elevated crystallization temperatures and crystallization rates, which were due to the heterogeneous nucleation of the submicron-sized ABS particles. In addition, it was observed that the theory by Mo suitably described the nonisothermal crystallization process. The activation energy slightly decreased for ABS contents of 5 and 15 wt % and then increased for a content of 25 wt %, indicating that the ABS promoted the crystallization of the blends at appropriate contents.