Abstract
Rhenium octahedral cluster complexes were immobilized into the cages mesoporous chromium(III) terephthalate MIL-101 in two ways: by the inclusion of anionic clusters as guests and by the coordination of cluster complexes through ditopic organic ligands (4,4′-bipyridyl) to metal atoms of the framework. The influence of the cluster complex—metal-organic matrix type of bonding on luminescence and sorption properties was studied. It was shown that the intensity of luminescence of the hybrid compound in which the cluster complexes are coordinated through ditopic organic ligands is considerably lower than that of the inclusion compound of cluster complexes in the coordination polymer cages.
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