Abstract

Abstract By utilizing lattice oxygen of a reducible metal oxide (a.k.a. redox catalyst), chemical looping reforming (CLR) partially oxidizes methane to syngas without gaseous oxygen. Subsequent to methane partial oxidation (POx), the reduced metal oxide is re-oxidized with air to complete the two-step redox cycle. In essence, CLR accomplishes methane POx without the need for an air separation unit, offering a potentially more efficient route for syngas production. This study investigates Rh promoted and iron/strontium doped CaMnO3 as redox catalysts at relatively low temperatures (

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