Rh(ii)-Catalyzed denitrogenative 1-sulfonyl-1,2,3-triazole-1-alkyl-1,2,3-triazole cross-coupling as a route to 3-sulfonamido-1H-pyrroles and 1,2,3-triazol-3-ium ylides

Abstract

The reaction of 1-alkyl-1H-1,2,3-triazoles with rhodium(ii) azavinyl carbenes, generated from 1-sulfonyl-1H-1,2,3-triazoles, was utilized to prepare 3-sulfonamido-1H-pyrroles and 1,2,3-triazol-3-ium ylides in good yields.