RGO-ZnO nanocomposites as efficient photocatalyst for degradation of 4-BP and DEP using high temperature refluxing method in in-situ condition

Abstract

Persistent organic pollutants (mainly aromatic compounds) such as bromophenol and diethyl phthalate are dangerous and act as primary contaminants in aqueous system. In this study, efficient reduced graphene oxide zinc oxide (rGO-ZnO) nanocomposites were synthesized by using a simple and facile method for photocatalytic degradation of 4-Bromophenol (4-BP) and diethyl phthalate (DEP). The rGO-ZnO (rGZ) nanocomposites (NCs) with different weight ratio of rGO and ZnO (coded as rGZ-1, rGZ-2, rGZ-5 and rGZ-10) were synthesized via high temperature refluxing method. The crystalline structure and phase, surface morphological study, optical properties, crystal defects and existence of functional groups in rGZ NCs were studied by X-ray diffraction (XRD), field-emission-scanning electron microscope (FE-SEM), UV-Visible diffuse reflectance spectroscopy (DRS), Raman spectroscopy and FT-IR analysis, respectively. The elimination of 4-BP and DEP from water by UV-light exposure was considered to estimate the photocatalytic efficiency of prepared rGZ NCs. The maximum elimination of 4-BP and DEP via photodegradation (advanced oxidation process) was found about 99.04% and 98.63% over rGZ NCs after 180 min UV irradiation, respectively. The photodegradation study was examined by using high performance liquid chromatography (HPLC) technique. This study confirms the efficient photocatalytic activity of rGZ-5 towards degradation of 4-BP and DEP. Finally, degradation mechanism has been proposed for the degradation of 4-BP and DEP.