Abstract
The possibility of using aluminum alkyls for the growth of acetylene oligomerization was studied utilizing an addition reaction different from the Aufbau reaction of ethylene. The investigations included exposing toluene solutions of AlEt 3 to acetylene at a pressure of 1 bar gauge, which resulted in double insertion in Al-hexadienyl groups. AlMe 3 exposed to acetylene under the conditions of 100°C and 1 brag acetylene show a dominant oligomer distribution made up of propane, 1,3-pentadiene, C 9, C 13, and C 17 products. It is also found that oligomerization of AlEt 3 follows removal of the volatiles under vacuum and formation of C 10+ fractions as a yellow liquid. The distribution of oligomers can be explained by a model whereby the rate of addition across the double bond is significantly greater than that for insertion.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Disclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.