Abstract
8′- O-(3-Hydroxy-3-methylglutaryl)-8′-hydroxyabscisic acid is a stable conjugate of the first metabolite of abscisic acid, 8′-hydroxyabscisic acid, that is spontaneously isomerized to phaseic acid. The chirality of the 3-hydroxy-3-methylglutaryl group of the conjugate was revised to S based on an HPLC analysis of the diastereomer derived from mevalonolactone obtained by reduction of the conjugate with lithium borohydride.
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