Abstract

The atomic-emission spectrum of four times ionized xenon (Xe V) has been observed in the region 500–6700 Å; 233 lines were classified as transition between 5s5p 3, 5s 25p5d, 5s 25p6s with 5s 25p 2, 5s 25p6p and 5s 25p4f configurations. Ninty-seven of these lines are reported for the first time. Two new energy level values corresponding to the 5s 25p4f configuration have been determined, and we proposed two new values for the previously reported 3D 1 and 3G 5 energy levels of this configuration. The value of the 5s 25p6p 1S 0 energy level has also been determined, and we propose a new value for the previously reported 5s 25p5d 3F 4 energy level. New adjusted values for the previously known levels of the studied configurations are included. Least-squares fitted parametric calculations involving configuration interactions have been carried out to interpret the observed spectrum.

Highlights

  • The spectrum o f four tim es ionized xen on (Xe V) has the ground configuration 5s25p2, the sam e as Sn I

  • Several ionic UV-visible Xe lines were charge-state assigned to Xe V by Duchow icz et al[5] but not classifications

  • A work concerning 5s25 p 5 d -5 s25p4f and 5s5 p 3- 5 s 25p4f transitions, estab lish in g 10 new levels o f the 5s25p4f configura­ tion, the rem aining 3F 4 level o f 5s25p5d and the classification o f several knownXeV laser fines, w as reported by Larsson et al,[9] using collision-based spectroscopy

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Summary

IN TRODUCT IO N

There is great interest in spectroscopy data from xenon due to applications in collision physics, high-temperature plasm as and laser physics. A work concerning 5s25 p 5 d -5 s25p4f and 5s5 p 3- 5 s 25p4f transitions, estab lish in g 10 new levels o f the 5s25p4f configura­ tion, the rem aining 3F 4 level o f 5s25p5d and the classification o f several knownXeV laser fines, w as reported by Larsson et al,[9] using collision-based spectroscopy. W ith the final goal of com pleting the classification o f the m ost prominent UV-visible Xe laser fines, we have continued an investigation o f the Xe V spectrum that concerns the study o f the energy levels in the configuration 5s25p4f, and the transitions 5s5p 3- 5 s 25p4f, 5s25 p 5 d -5 s25p4f, 5 s25 p 6 s-5 s25p4f, and the classification o f fines b elo n g in g to transitions betw een the 5s25p6p configuration with odd parity configurations

EXPERIM EN T
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