Review on the recent advances on ammonia combustion from the fundamentals to the applications

Abstract

As a fueling vector, ammonia is gaining more interest for future power generation, transportation and heating systems. Compared to typical hydrocarbons, ammonia's low reactivity characteristics and higher NOx emissions limit its practical implementation. However, the current need for decarbonization of the energy sector puts ammonia as an energy vector and carrier at the far front, making overcoming the challenges of ammonia utilization necessary. In late 2018, Kobayashi et al. presented a review article on the science and technology of ammonia combustion. In continuing their effort, this review is aimed towards giving the most recent updates in ammonia combustion. The article starts with the importance of ammonia as an energy carrier and covers the fundamentals of ammonia combustion. We then present recent activities for addressing the low ammonia reactivity and its impact on NOx emissions. In addition, the chemical kinetics of ammonia oxidation is presented through a discussion of recently proposed chemical kinetics mechanisms. This section emphasizes the role of crucial reaction differences, the updates in the NOx and De-NOx pathways, NHi recombination reactions and H2NO chemistry. Towards utilising ammonia in gas turbines and industrial applications, this review discusses recent efforts and various NO mitigation strategies. This work systematically summarizes the fundamentals of ammonia-based combustion and its application. It serves as a reference for the transition of ammonia into future practical applications.