Abstract
d-block metals show great promise in inorganic catalytic research. Particularly, copper, d9 metal has contributed to catalytic properties of its complexes. A series of copper complexes was synthesized and structurally characterized. The copper (I) complexes of this series were investigated in regard to their reactivity towards dioxygen using stopped-flow techniques. For most complexes no “oxygen adduct” complexes as intermediates could be detected. In this article, some complexes of Cu (I) have been included and the ligands on which work had been done are mentioned below: 1,5-bis(benzimidazole-2-yl)-3-thiapentane Tridentate di-pyrazole -3,6-di-tert-butyl-carbazole (N, N, N-Pincer ligand) Methyl isocyanate N4Cu Tris(pyrazolyl) hydroborate ligand Scorpionate ligand Phenanthroline Tripodal amine ligands Triazole derivatives Keywords: BBES (1,5-bis(benzimidazole-2-yl)-3-thiapentane), MeIN (Methyl isocyanate), CuSCN (copper thiocyanate), PPh3(triphenyl phosphine), PCy3(tricyclohexyl phosphine), TptBuPh (tris[3-(p-tert-butylphenyl)], Tp (tris pyrazolyl hydroborate), Me4-p,3,3 (3,3-dimethylaminopropyl-(2-methylenpyridyl)-amine), Me2-pp3 (3-dimethylaminopropyl-bis(2-methylenpyridyl)-amine)
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