Abstract
A molecular Ni(II)–NNN pincer complex (1) exhibited unprecedented reversible single-crystal-to-single-crystal transformation and color change upon heating and cooling due to a subtle change in the N–Ni(II) bond length and ligand conformation. UV–vis, thermogravimetric, differential scanning calorimetry, single-crystal structural data, temperature-dependent powder X-ray diffraction, and Raman and computational studies supported the structural change of the Ni(II) complex with temperature.
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