Abstract
AbstractSummary: A membrane of a cobalt tetraazaporphyrin polymer complex was prepared with a nanometer thickness and used as an oxygen‐facilitated transport membrane. Rapid and reversible oxygen binding to the cobalt tetraazaporphyrin complex with a polymeric imidazole ligand was observed at low temperature. Oxygen transport through the membrane was facilitated and a high (oxygen/nitrogen) permselectivity of 28 was obtained.Oxygen‐facilitated transport through a cobalt tetraazaporphyrin complex‐polymer membrane of nanometer thickness.imageOxygen‐facilitated transport through a cobalt tetraazaporphyrin complex‐polymer membrane of nanometer thickness.
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