Abstract
Reversible solid-state structural transformation of sodium(I) coordination polymer nanorods, prepared by sonochemical procedure, to organosilver coordination polymer nanosheets has been observed upon liquid assisted mechanochemical reaction of compound [Na2(1,5-nds)(H2O)2]n (1), [1,5-H2nds=1,5-naphthalenedisulfonic acid] with AgNO3. During this conversion, two coordinated H2O molecules were removed from 1 and substituted with two carbon atoms from 1,5-nds2− ligand in 2. Thus organosilver coordination polymer of 2 was formed during this conversion and distorted trigonal-bipyramidal coordination geometry in 1 with NaO5 coordination sphere was converted to distorted tetrahedral geometry in 2 (regarding the CC group as one donor) with AgO3C2 coordination sphere.
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