Reversible hydrochromic CsPbBr3/Cs4PbBr6@MCM-41 to enable organic solvent polarity detection

Abstract

Hydrochromic materials have received much attention in anticounterfeiting due to their reversible photoemission properties toward water. However, existing hydrochromic materials usually suffer from slow hydrochromic response and limited stability, repeatability, and color tunability. This paper found for the first time that CsPbBr3/Cs4PbBr6 composites with quantum-limited domain effects had reversible hydrochromism. CsPbBr3/Cs4PbBr6 composites were successfully synthesized in molecular sieve MCM-41 using an improved mechanochemical method. The composites underwent a reversible phase transition from Cs4PbBr6/CsPbBr3 to CsPbBr3 upon treatment with a trace amount of water, the photoluminescence colors underwent a change from blue to green, and reversion occurred due to heating. Mechanistic investigation revealed that quantum dots underwent soft agglomeration due to van der Waals forces in polar solvent environments, affecting the action of quantum domain-limiting effects. Therefore, organic solvents with different polarities can cause different degrees of reversible discoloration of the material. This study provides new ideas for understanding the phase transition and agglomeration of metal halide perovskite quantum dots in polar solvent environments. Additionally, it offered new options for aqueous color-changing materials and organic solvent polar detection materials.