Abstract

Abstract Extensive doping of poly(2,5-thienylene) (PTh) with iodine gives rise to a new crystal form with d value of 1.00, 0.49, 0.32, and 0.25 nm. Undoping of the iodine-doped PTh with N2H4 leads to recovery of original crystal structure of PTh, showing that rearrangement of PTh molecules after the undoping is very smooth.

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