Revealing the impact of isolated pores on the properties of foam cement using hollow microspheres

Abstract

Since foam concrete inevitably leads to foam bursting and merging during the molding process, the relationship between specific pore connectivity and pore diameter distribution on foam concrete properties is still difficult to characterize exactly. This study intentionally introduced hollow microspheres of three sizes (40 µm, 60 µm, and 80 µm) into foam concrete to control the number and diameter of isolated pores. The influence of isolated porosity and pore diameter distribution on the properties of foam concrete were evaluated by dry density, mechanical property and thermal conductivity. Meanwhile, the SEM and X-CT technologies were employed to assess the pore structure of the sample, and the measured thermal conductivity was compared with the theoretical thermal conductivity calculated by the formula based on the isolated porosity. Finally, the correlation between isolated pores and heat transfer paths were analyzed by the calculated tortuosity. The results of the dry density and mechanical tests indicated that the dry density tended to be lower with the increase of isolated pores’ diameter, which 80 µm hollow microspheres resulted in a notable reduction in the dry density within the three size groups, whereas 28 days compressive strength trended oppositely. The 40 µm hollow microsphere specimen with a dry density of 400 kg/m3 exhibited the better mechanical property among three groups, which was 1.82 MPa, due to the uniform distribution within the matrix, preventing fusion between foams. Specifically, the trend of the theoretical value calculated by the formula was consistent with that of the measured value, proving that the decrease in thermal conductivity of sample can be attributed to the increase of isolated porosity. The lowest thermal conductivity and highest tortuosity were achieved by specimens mixed with 80 µm hollow microspheres at the dry density of 300 kg/m3, which were 0.07045 W/(m·K) and 2.015, respectively, demonstrating that specimens mixed with 80 µm hollow microspheres exhibited a more complex heat transfer path than the other two groups.