Abstract
AbstractSodium‐ion batteries are one of the most promising candidates for large‐scale energy storage. Manganese‐based layered oxides are extensively studied as a cathode of sodium‐ion batteries due to the low cost and high electrochemical activity. However, these layered cathodes usually suffer from the severe manganese dissolution originated from Jahn–Teller distortion, thereby leading to severe capacity fading and structural deterioration. Herein, it is demonstrated via a combined experimental and theoretical study, titanium substitution in layered manganese‐based oxides can weaken the Jahn–Teller effect, minimize the relative dissolution, and thus enable robust sodium storage during long‐term operation. Results reveal that Ti‐doping can restrain shrinkage or elongation of the MnO octahedral structure to minimize the Jahn–Teller distortion for Mn atoms surrounded by titanium. Consequently, P2‐Na0.86Co0.475Mn0.475Ti0.05O2 can deliver a reversible capacity over 110 mAh g−1, good rate capability, and superior long‐cycling performance (81.1% cycle retention after 200 cycles at high rate of 5 C). The findings provide new opportunities for design of high‐performance electrodes for sodium‐ion batteries and deepen the understanding of intercalation chemistry in layered structures.
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