Revamping a Classic Analytical Chemistry Laboratory Experiment to Improve Student Understanding of Chemical Analysis, Method Development, Validation, and Statistics

Abstract

We have revamped a classic analytical chemistry laboratory experiment, “Determination of an Unknown Acid”, to provide students an opportunity to learn about new advances in the material sciences and their applications in analytical chemistry in an effort to reinforce the key concepts of chemical analysis. Specifically, students were given the opportunity to develop their own low-cost, low-maintenance, ease-of-use, multidimensional pH sensor with intrinsically conducting polyaniline material. The students tested their polyaniline pH sensor against the traditional glass pH electrode to determine an unknown acid concentration and performed statistical tests to validate the analytical capabilities of their electrochemical polyaniline pH sensor. Thus, the revamped laboratory experiment allows for the reinforcement of several fundamental analytical chemistry lecture concepts, including chemical analysis, method development, validation, and statistical practice utilizing a more cohesive hands-on laboratory learning approach. Furthermore, this revamped lab gives students the opportunity to evaluate and compare the analytical performance of the polyaniline pH sensor, such as its sensor lifetime against the glass pH electrode, and learn polyaniline’s electrochromic properties. This laboratory experiment can be easily disseminated to advance the objective of analytical curriculum, provide students an opportunity for multidimensional learning and well-connected critical thinking in analytical chemistry, and stimulate students’ creativity in developing next generation analytical sensor technology.