Abstract

Abstract. An algorithm has been developed for the retrieval of sodium atom (Na) number density on a latitude and altitude grid from SCIAMACHY (SCanning Imaging Absorption spectroMeter for Atmospheric CHartographY) limb measurements of the Na resonance fluorescence. The results are obtained between 50 and 150 km altitude and the resulting global seasonal variations of Na are analyzed. The retrieval approach is adapted from that used for the retrieval of magnesium atom (Mg) and magnesium ion (Mg+) number density profiles recently reported by Langowski et al. (2014). Monthly mean values of Na are presented as a function of altitude and latitude. This data set was retrieved from the 4 years of spectroscopic limb data of the SCIAMACHY mesosphere and lower thermosphere (MLT) measurement mode (mid-2008 to early 2012). The Na layer has a nearly constant peak altitude of 90–93 km for all latitudes and seasons, and has a full width at half maximum of 5–15 km. Small but significant seasonal variations in Na are identified for latitudes less than 40°, where the maximum Na number densities are 3000–4000 atoms cm−3. At middle to high latitudes a clear seasonal variation with a winter maximum of up to 6000 atoms cm−3 is observed. The high latitudes, which are only measured in the summer hemisphere, have lower number densities, with peak densities being approximately 1000 Na atoms cm−3. The full width at half maximum of the peak varies strongly at high latitudes and is 5 km near the polar summer mesopause, while it exceeds 10 km at lower latitudes. In summer the Na atom concentration at high latitudes and at altitudes below 88 km is significantly smaller than that at middle latitudes. The results are compared with other observations and models and there is overall a good agreement with these.

Highlights

  • The metal sodium, Na, was first isolated in the laboratory by Sir Humphry Davy in 1807 (Davy, 1808)

  • Na has a large number density compared to other metals in the mesosphere and lower thermosphere (MLT), and the lower atmosphere is nearly transparent at the wavelength of the strongest Na transitions at 589 nm

  • The retrieval algorithm presented in Langowski et al (2014), which was used for magnesium atom and ion retrievals from the SCIAMACHY limb MLT measurements (Langowski et al, 2015), is used and adjusted to the specific parameters of Na atoms

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Summary

Introduction

The metal sodium, Na, was first isolated in the laboratory by Sir Humphry Davy in 1807 (Davy, 1808). The metals are readily observed by remote sensing methods Due to their strong radiation signal and their relatively long atmospheric lifetime, metal species are used as trace species to investigate wave propagation effects and winds in the mesosphere and lower thermosphere (MLT). Na has a large number density compared to other metals in the MLT, and the lower atmosphere is nearly transparent at the wavelength of the strongest Na transitions at 589 nm. This simplifies the observation from the ground. Results of the Na number density retrieval from the SCIAMACHY limb MLT measurements between 2008 and 2012 are presented in this study.

SCIAMACHY
Retrieval algorithm and adaption to Na
Forward model for the single scattering algorithm
Discretization of the forward model and calculation of the Jacobian
Calculation of path matrices
Inversion of the forward model
Extension for multiple scattering
Monthly averaged Na densities
50 J FMAMJ J ASOND J J FMAMJ J ASOND J
Estimation of errors in the vertical profile
Differences between D1 and D2 retrieval results
Comparison to independent data sets
Findings
Conclusions
Full Text
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