Abstract
With the development of computer operation technology and algorithms, the lumped dynamic model is more practical, and the development and application are more comprehensive. Among them, the direct coal liquefaction residual oil pyrolysis and coking technology, as a coal‐to‐liquid process, can increase the oil yield of the coal liquefaction process and reduce environmental pollution. The purpose of this paper is to study the experiment and algorithm of coal direct liquefaction residual oil pyrolysis and coking technology based on lumped kinetic engineering. Starting from the lumped kinetic engineering, this paper takes the direct coal liquefaction residual oil pyrolysis and coking technology as the research object. Based on the experiment of small‐ and medium‐sized equipment, the residual oil pyrolysis and coking experiment is carried out. This paper further analyzes the components of the experimental products and explores the factors that affect the yield of residual pyrolysis oil based on the five lumped kinetic model of coking. Experimental data shows that when the pyrolysis temperature is 450°C, the content of liquefied heavy oil HS in the pyrolysis oil is 47.87%, the content of asphaltene A is 44.28%, and the content of preasphaltene PA is 7.85%; the pyrolysis temperature is 500 °C. At this time, the content of liquefied heavy oil HS in the pyrolysis oil is 54.97%, the content of asphaltene A is 40.23%, and the content of preasphaltene PA is 4.8%. It can be seen that, with the increase of pyrolysis temperature, the content of liquefied heavy oil HS increases, and the content of asphaltene A and preasphaltene PA decreases.
Highlights
Direct coal liquefaction residual oil pyrolysis and coking technology, as a coal-to-liquid process, effectively provide important technical support for ensuring our country’s energy supply and safety, alleviating our country’s shortage of petroleum resources and other prominent and sensitive issues [1,2]
The existing coal rapid pyrolysis and coking process still faces problems such as low coal utilization, poor tar quality, and reprocessing pyrolysis of the liquefied residue generated at the end of the hydrolysis process [3,4]. e research on the experiment and algorithm of coal direct liquefaction residual oil pyrolysis and coking technology based on lumped kinetic engineering will help to provide a new solution to this type of problem [5,6]
Erefore, research on the experiment and algorithm of coal Journal of Mathematics direct liquefaction residual oil pyrolysis and coking technology based on lumped kinetic engineering has important theoretical and practical significance
Summary
Direct coal liquefaction residual oil pyrolysis and coking technology, as a coal-to-liquid process, effectively provide important technical support for ensuring our country’s energy supply and safety, alleviating our country’s shortage of petroleum resources and other prominent and sensitive issues [1,2]. E purpose of this paper is to study the experiment and algorithm of coal direct liquefaction residual oil pyrolysis and coking technology based on lumped kinetic engineering. The experiments are performed and the algorithm of coal direct liquefaction residual oil pyrolysis and coking technology has been proposed which is based on lumped kinetic engineering. To this end, the factors affecting coal pyrolysis are presented. Where kB is the Boltzmann constant, h is the Planck constant, T is the temperature, R is the ideal gas constant, ΔSm is the entropy change before and after the reaction, and ΔE is the reaction energy barrier. erefore, knowing ΔSm and ΔE, the reaction rate constant at the specified temperature can be calculated
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