Abstract
Rational design, synthesis, and structural determination of 3D covalent organic frameworks (COFs) with novel topologies remain a formidable challenge. In this issue of <i>Chem</i>, Zhang and co-workers develop an intriguing strategy for constructing highly crystalline and non-interpenetrated 3D porphyrinic COFs with <b>scu</b> topology and possessing some excellent photocatalytic efficiencies.
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