Abstract
In an effort to scrutinize dimensional restriction effects on finite hydrogen-bonded networks, we deposit ion-doped water clusters by computational soft landing on a chemically inert supported xenon surface. In stark contrast to the much studied metal or metal oxide surfaces, the rare gas surface interacts only rather weakly and nondirectionally with these networks. Surprisingly, the strongly bound Na+-doped networks undergo very significant plastic deformations, whereas the weakly bound Cl- counterparts barely change upon surface deposition. This counterintuitive finding is traced back to the significantly less favorable water-water interactions enforced by the cation, which results in an easier adaption to geometric restrictions, whereas H-bonding stabilizes the anionic clusters.
Sign-in/Register to access full text options 
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
