Response Surface Method Based Modeling and Optimization of CMC-g Terpolymer Interpenetrating Network/Bentonite Superabsorbent Composite for Enhancing Water Retention.

Abstract

Water shortages have become a serious issue, so the importance of developing innovative cellulose-based superabsorbent polymer (SAP) was experimentally assessed as an environmentally friendly alternative to acrylate-based SAPs for the optimization of water consumption. The development of a biodegradable superabsorbent hydrogel composite based on a graft copolymer of carboxymethyl cellulose (CMC) and mixtures of different comonomers such as an acrylamide-co-acrylic acid-co-2-acrylamido-2-methylpropanesulfonic acid (Am-co-AA-co-AMPS) CMC-g-TerPoly interpenetrating network was characterized by infrared spectroscopy (FT-IR), scan electron microscopy (SEM), atomic force microscope (AFM), thermal gravimetric analysis (TGA), and swelling capacity in different aqueous media. The optimized CMC-g-(TerPoly) composite showing outstanding superabsorbance with high water retention, the ratio of constituents, temperature, and pH effect on equilibrium swelling have been optimized by using multistage response surface methodology (RSM). In distilled water (d-water), the equilibrium water absorption capacity (EW) of the synthesized composite hydrogels (SAP-IPN1) is 1200 g (d-water/1g hydrogel) which is superior to any other commercial polyacrylate SAP hydrogels, while in saline water the EW is 650 g (s-water/1g hydrogel). The performance of the SAP-IPN for water retention was evaluated by studying several swelling/deswelling cycle measurements. The prepared SAP-IPN hydrogels were found to show pH and salt solution dependence on the swelling behavior. The new SAP-IPN can work with commercial SAP, which is recommended for application as a water reservoir in arid land for irrigation for agriculture purposes.