Resource utilization strategies for spent pot lining: A review of the current state

Abstract

During a long-term operation of the aluminum electrolysis cell, the molten salts continuously infiltrate and corrode the pot lining, resulting in a huge amount of hazardous waste after the overhaul. The first cut of spent pot linings (SPL) contains several carbon-rich materials with potential economic value and hazardous matters such as soluble fluorite and cyanide. The continuous accumulation and disposal of SPL in depots or landfills have created a severe challenge to the aluminum industry. Nowadays, the technologies of harmless disposal and resource utilization of SPL have been paid more attention. This work has explored and presented the properties of SPL (including chemical, physical, and thermodynamic properties, etc.) and methods for its detoxification and purification. In this regard, the resource utilization strategies of SPL are systematically sorted out from three aspects: traditional, co-processing, and high-value technologies. In the end, the current challenges and future perspectives for the environmental recycling of SPL have been analyzed and summarized.