Resource utilization of semi-dry flue gas desulfurization ash by thermal treatment on sintering machine

Abstract

Semi-dry flue gas desulfurization ash (SFGDA) is an abandoned Ca and S resource that is currently stacked without appropriate disposal methods. A technology with industrialization potential, SFGDA, and iron ore thermal processing is an effective approach to obtaining calcium ferrite and industrial sulfuric acid. This study investigated the thermochemical reaction mechanism of SFGDA during high-efficiency pyrolysis employing Fe2O3 and coke powder for self-heating. The results showed that the addition of coke powder enhanced the thermal efficiency and reduced the decomposition temperature, while the reaction is accelerated by the lightning-fast combination of Fe2O3 with the CaO produced during pyrolysis to generate calcium ferrite products. The optimal conditions were determined to be a coke powder dosage of 10% and Fe2O3 dosage of 50%. In semi-industrial experiments, the SFGDA achieved a desulfurization rate of 99% and a calcium ferrite content of 85%. The calcined product CaO from CaSO4 and CaSO3 in the form of calcium ferrite products, with a minimal amount of CaSO4. In addition, during the high-temperature calcination process performed by the sintering machine, the majority of the sulfur within the raw materials migrates as SO2 and is subsequently emitted into the flue gas. Following, this SO2 is captured and utilized for the production of commercially valuable sulfuric acid. When the yield of enabled to calcined product corresponds to 1 ton, it could potentially dispose of 882 kg of SFGDA, culminating in a high-value, harmless, and large-scale SFGDA treatment in steel industry.