Resource scarcity in palladium membrane applications for carbon capture in integrated gasification combined cycle units

Abstract

Abstract Recently, many reviews on pre-combustion CO 2 capture (CCS) in an IGCC plant have been focused on the techno-economic performance of palladium-based membrane reactor modules downstream of conventional steam reforming or shift reactors. Although the determination and minimisation of the amount of palladium necessary for a specific power production capacity has been the target of many research studies, surprisingly little attention has been paid in the open literature to the availability of this metal in the large quantities required for large scale applications. To fill this gap, the scope of this work was to compare the amount of palladium needed for pre-combustion CCS with Pd-membranes and the available production capacity of palladium. Two specific techno-economic studies with a different net IGCC power output were selected from the literature. In each case, the amount of palladium that is necessary for the plant to be in operation was compared with the world supply and demand for palladium. The results show that even for a power plant of “only” 1 GWe net electricity production utilizing membranes with the best reported performance, a relatively large (∼0.7%) amount of palladium is required compared to the total world supply. Considering the total worldwide electricity production from fossil fuels (14,455 TWh in 2010) a tremendous increase in the world supply of Palladium would be required to redirect from the traditional IGCC power plants without CO 2 capture units to the new membrane technology. We conclude that large scale pre-combustion capture of CO 2 using palladium membranes seems to be unfeasible and research on Pd-based membrane reactors should focus on small(er) scale applications.