Resonance Raman spectra of Cu‐porphin‐d4(meso) and Ni‐porphin, and the infrared spectrum of Cu‐porphin‐d4

Abstract

AbstractThe resonance Raman spectra are presented for Ni‐porphin and Cu‐porphin‐d4(meso) as dilute solutions in CS2 and C2Cl4 using an Ar+ laser and a tunable Rhodamine 6G dye laser. The Raman features are assigned to the different vibrational species on the basis of their depolarization data. The assignment of 14 features in the spectrum of Cu‐porphin‐d4 and 13 features in the spectrum of Cu‐porphin and Ni‐porphin is discussed by comparing the spectra of the three molecules. Also the infrared spectrum of Cu‐porphin‐d4 as a solid dispersed in CsI matrix is reported for the 200–2000 cm−1 region.