Abstract

The results of recent mass-resolved resonance enhanced multiphoton ionisation (REMPI) and REMPI-photoelectron spectroscopy (PES) studies of the sixteen valence electron molecules OCS and CS 2 are used to illustrate some of the many opportunities offered by (and a few of the possible limitations associated with) these techniques when applied to studies of the spectroscopy and the decay dynamics of small molecules in excited electronic states.

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