Resolution of the forbidden (J= 0 → 0) excitation puzzle in Mg-like ions

Abstract

We have carried-out 98-level configuration-interaction / close-coupling (CI/CC) intermediate coupling frame transformation (ICFT) and Breit-Pauli R-matrix calculations for the electron-impact excitation of Be-like Al$^{9+}$. The close agreement that we find between the two sets of effective collision strengths demonstrates the continued robustness of the ICFT method. On the other hand, a comparison of this data with previous 238-level CI/CC ICFT effective collision strengths shows that the results for excitation up to n=4 levels are systematically and increasingly underestimated over a wide range of temperatures by R-matrix calculations whose close-coupling expansion extends only to n=4 (98-levels). Thus, we find to be false a recent conjecture that the ICFT approach may not be completely robust. The conjecture was based upon a comparison of 98-level CI/CC Dirac R-matrix effective collision strengths for Al$^{9+}$ with those from the 238-level CI/CC ICFT R-matrix calculations. The disagreement found recently is due to a lack of convergence of the close-coupling expansion in the 98-level CI/CC Dirac work. The earlier 238-level CI/CC ICFT work has a superior target to the 98-level CI/CC Dirac one and provides more accurate atomic data. Similar considerations need to be made for other Be-like ions and for other sequences.