Abstract

The gas chromatographic resolution of racemic amino acids as their N-trifluoroacetyl esters was carried out on an optically active stationary phase. Relation between the sepa-ration factor and structure of racemic amino acids, and relative retention times were studied. It is concluded that the separation factor of racemic amino acids depends on the relative size of the substituent on the asymmetric carbon and the position of amino group.

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