Abstract
Some racemic unsaturated hydrocarbons, 3- and 4-methyl and 4-vinylcyclohexene, bicyclo[4.3]nonane-2,5-diene, and 3-chloro- and 3,4-dichloro-1-butene were resolved as inclusion complex crystals with a chiral host compound derived from tartaric acid. The inclusion complexation, purified by repeating recrystallization from ether twice and decomposed by heating in vacuo, gave optically active hydrocarbons of 28–75% ee by distillation. The optical resolution by inclusion complexation in a water suspension medium and by fractional distillation in the presence of a chiral host was also applied to these hydrocarbons.
Talk to us
Join us for a 30 min session where you can share your feedback and ask us any queries you have
Schedule a callDisclaimer: All third-party content on this website/platform is and will remain the property of their respective owners and is provided on "as is" basis without any warranties, express or implied. Use of third-party content does not indicate any affiliation, sponsorship with or endorsement by them. Any references to third-party content is to identify the corresponding services and shall be considered fair use under The CopyrightLaw.
