Abstract
By using the Corey diamine 1,2-diphenyl-N,N′-bis[(2,4,6-trimethylphenyl)methyl]-1,2-diaminoethane, Copper(I) olefin complexes are prepared. When the olefin is a racemic allylic alcohol, selective coordination of one enantiomer is observed. Cleavage with aqueous HCl or NaCN allows a two-steps resolution affording excellent enantiomeric excess.
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