Abstract
Layered rare-earth hydroxides (LRHs), which have the general composition RE<sub>2</sub>(OH)<sub>5</sub>X·<italic>n</italic>H<sub>2</sub>O (where RE=rare-earth elements and X=anion), are a new group of important two-dimensionally inorganic layered matrices. The combination of various rare-earth and exchangeable ions is a unique feature of this layered rare-earth hydroxides family, which makes LRHs to be a kind of potential new functional materials. Herein, the research progresses of hybrid luminescent materials based on the layered rare-earth hydroxides have been reviewed. The effects of the host-guest interactions on the photophysical behaviors and stabilities of the hybrid materials have also been discussed.
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