Abstract

Phosphogypsum is a kind of solid waste which pollutes the environment without reasonable treatment. The application of phosphogypsum in the field of building materials provides an ideal method to solve this problem. Meanwhile, the phosphogypsum mixed with foam can be used for the thermal insulation of wall materials. This paper aims to study the influence of foam volume and cement content on the thermal conductivity, water resistance coefficient and the mechanical strengths of foamed phosphogypsum. The volume of foam in this study ranged from 0% to 60%. Moreover, the influences of humidity and cement content on the mechanical strengths of phosphogypsum are investigated. Scanning electron microscope and the mercury intrusion porosimetry are used for the microscale research and analysis. Results indicate that the relationships between the parameters (thermal conductivity, water resistance coefficient and mechanical strengths) and foam volume fit well with a negatively correlated linear function. The addition of cement can improve the compactness of phosphogypsum and decrease the diameter and volume of pores. Therefore, the thermal conductivity, water resistance coefficient and mechanical strengths of phosphogypsum are increased by the addition of cement.

Highlights

  • IntroductionPublisher’s Note: MDPI stays neutral with regard to jurisdictional claims in published maps and institutional affiliations

  • (1) The relationships between these parameters and foam volume of phosphogypsum can be desistance coefficient and the mechanical strengths) and foam volume of phosphogypsum scribed as a linear function well

  • The addition of cement demonstrates positive correlation can be described as a linear function well

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Summary

Introduction

Publisher’s Note: MDPI stays neutral with regard to jurisdictional claims in published maps and institutional affiliations. Phosphogypsum is a byproduct of wet process phosphoric acid. Each ton of phosphoric acid produced produces 5 tons of phosphogypsum. Phosphogypsum is produced and stored as industrial waste in the yard. The main component of phosphogypsum is CaSO4 ·2H2 O. If this kind of material is properly treated, the phosphogypsum is a rich source of gypsum. Impurities such as phosphorus, sulfate, fluoride, residual acid and heavy metals have affected the normal utilization of phosphogypsum

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