Research on the synergistic flame retardation of epoxy resin through surface-modified aluminum diethylphosphinate in conjunction with DOPO and CFA

Abstract

Surface modification of aluminum diethylphosphinate (ADP) was successfully achieved through the utilization of silane coupling agent KH-560. Simultaneously, the modified aluminum diethylphosphinate (K-ADP) served as the primary flame retardant, with 9,10-dihydro-9-oxa-10-phosphaphenanthrene-10-oxide (DOPO) as the phosphorus-based flame retardant and charring‐forming agent (CFA) as the nitrogen-based synergistic flame retardant. This approach was employed to investigate the flame-retardant modification of epoxy resin. The optimal dosage of the surface modifier was investigated through moisture absorption test and viscosity measurements. Synergistic flame-retardant interactions among K-ADP, DOPO, and CFA were examined using techniques such as cone calorimetry test, thermogravimetric analysis, and residual char infrared analysis. The results indicated that the optimal dosage of KH-560 is 5%, resulting in a significant reduction in moisture absorption to 0.195%. At 80 °C, the addition of K-ADP leaded to only a 22.7% increase in system viscosity, demonstrating a notable viscosity reduction effect. When the addition of K-ADP is 14%, the Limiting Oxygen Index (LOI) value reached 30.5%, achieving a V-0 rating. Moreover, by maintaining the total addition at 14% and introducing DOPO and CFA, it is evident that most of samples meet UL-94 V-0 rating, with the LOI elevated to 32.2%. CCT results indicated a significant decrease in both average heat release rate and total smoke production, reduced by 24.1% and 7.0%, respectively. This notably enhanced the flame-retardant and smoke-suppressant properties of the EP composite material. The addition of K-ADP, DOPO, and CFA improved the mechanical performance of the EP composite material, surpassing the effectiveness of adding ADP individually.