Abstract

In this study, a series of bifunctional-based UV curable waterborne polyurethane acrylate modified epoxy acrylate (UV-WPUA) was prepared by using 2,4-toluene diisocyanate (TDI), Epoxy resin (E51) and polyethylene glycol (PEG) as the main materials. Waterborne resin and UV curing film with content of C-O-C were obtained by using polyethylene glycols with different molecular weights. The infrared spectra (FT-IR) demonstrated the presence of C=C and epoxy bond in the UV curing film chains. In addition, the molecular weight of the oligomer, and glass transition temperature, gelation rate and thermogravimetric analysis of the films were investigated.

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