Research on selective laser sintering process of ternary composite materials (PP/MCMB/CNT)

Abstract

The composite material composed of polypropylene and conductive filler has good corrosion resistance, light weight and good conductivity, and is one of the preferred materials for fuel cell bipolar plates. The formation of ternary composite materials composed of polypropylene, mesocarbon microbeads and carbon nanotubes is realized by selective laser sintering. The influences of laser power, scanning speed, scanning spacing and defocus amount on forming quality are studied. The formability of mixed powders with different composition proportions as well as the conductivity, bending strength and hydrophobicity of the formed samples are investigated. The results show that when the input energy density is insufficient, it is easy to form defects such as spheroidized particles and worm-like structures. The parameters with good forming quality are in the following range: defocus amount is + 3 mm; line energy density is 2.94–3.85 J/mm2; peak power density is 1.13 × 104-1.48 × 104 W/mm2 and scanning spacing is 0.1–0.14 mm. The conductive filler in composite material is beneficial to improving the conductivity, but it will reduce the formability of the mixed powders and reduce the bending strength and hydrophobicity of the sample. The effect of mesocarbon microbeads on improving conductivity or on reducing hydrophobicity is smaller than that of carbon nanotubes.